多组份电解质溶液热力学——活度系数和渗透系数与高次极限定律的关联

Thermodynamics of the Mixed Electrolyte Solution

中文关键词:  Pitzer,电解质溶液,溶液化学

英文关键词:Pitzer, Electrolyte Solution, Solution Chemistry,

中文摘要:

      自1973年Pitzer电解质溶液理论问世以来,它在海洋学、地球科学、生物学乃至化工中获得了广泛的应用。本文介绍在实际应用中有重要意义的高次极限定律及与活度系数、渗透系数间的关联,它们是Pitzer理论发展的重要组成部份。

英文摘要:

      Since Pitzer model of electrolyte solution was established in 1973, it has been widely used in oceanography, geoscience, biology and chemical engineering. In this paper highorder limit laws and its correlation with activity and osmotic coefficients are introducted as an important part of the development of the Pitzer model.