四价金属层状有机衍生物的合成和离子交换性质的研究Ⅱ:无定型混合组份4,4'-联苯基二膦酸锆/磷酸锆

Preparation and Properties of Layered Organic Derivatives of Tetravalent MetalsII:Amorphous Mixed Components Zirconium 4, 4'-Diphenyl Bisphospate /Phosphate )

中文关键词:  4，4'－联苯基二膦酸锆／磷酸锆,离子交换剂,MCZDPP系列化合物

英文关键词:Zirconium 4,4-diphenyl bisphosphate,MCZDPP,Ion exchanger property,

中文摘要:

      用４，４'－联苯二膦酸及磷酸的混合酸和Ｚｒ(４＋)共沉淀反应，制备无定型ＭＣＺＤＰＰ系列化合物。合成中以不同比例的混合酸构筑出具有相同组份，不同微孔的化合物，较ＭＣＺＰＰ化合物微孔更大。ＭＣＺＤＰＰ系列化合物是一种微晶聚集体，颗粒度较大，热稳定性好，是一类性能良好的多功能材料。

英文摘要:

      Zirconium 4, 4'-diphenyl bisphosphate/phosphate (MCZDPP) of amorphous mixedcomponents were synthesized. The compounds have the same components but differentmicropores and ion-exchange properties. The MCZDPP compounds are crystalline groupswith bigger size. They are thermally stable. As a type of superior material,they can be usedin various fields.