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四苯硼钠—季铵盐质量滴定法分析常量铷 |
Determination of Rubidium in High Concentrations by the Mass Titration with Sodium Tetraphenylboron-Quaternary Ammonium Salt |
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DOI: |
中文关键词: 铷 四苯硼钠 季铵盐 松节油 质量滴定 |
英文关键词:Rubidium Sodium tetraphenylboron Quaternary ammonium salt Turpentine Mass titration |
基金项目:国家自然科学基金项目(20773152); 青海省科技创新能力促进计划项目(2009-Z-725)资助 |
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中文摘要: |
采用四苯硼钠—季铵盐质量滴定法分析溶液中的常量铷,考察了松节油用量和共存离子(Ca2+、Mg2+、Li+、CO2-3、SO2-4、B4O2-7)对氯化铷溶液中Rb+分析结果的影响。溶液中Rb+浓度为0.05%~0.15%时,分析结果的相对误差〈0.3%,加标回收率为99.20%~101.2%。溶液中的共存离子Ca2+、Li+和SO2-4对Rb+分析无影响。 |
英文摘要: |
The rubidium in high concentrations was analyzed by the mass titration sodium tetraphenylboron -quaternary ammonium salt. The effects of turpentine drop number and coexisting ions including Ca2+ , Mg2+ , Li+ , CO3-, SO42- and B4O72- on the determination of rubidium were studied respectively. When the concentrations of Rb+ were from O. 05% to 0. 15% in weight, the relative error by this method was less than 0.3% ,and the samples recoveries were from 99. 16% to 101.52%. Coexisting ions,such as Ca2+ , Li+ , and SO42- have little impact on the analysis of rubidium using this method. |
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