铷和铯离子的提取分离技术研究进展
Research progress on the extraction and separation technology of rubidium and cesium ions
投稿时间:2023-05-11  修订日期:2023-06-25
DOI:
中文关键词:  铷/铯  浸出  焙烧  萃取  离子交换
英文关键词:rubidium/cesium  leaching  roasting  extraction  ion exchange
基金项目:
作者单位邮编
赵亮 浙江工业大学材料科学与工程学院 310014
王蒙蒙 中国科学院宁波材料技术与工程研究所 
夏永高 中国科学院宁波材料技术与工程研究所 
高洁* 中国科学院宁波材料技术与工程研究所 315201
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中文摘要:
      随着科技的高速发展,铷和铯因其优异的理化性质,应用范围不再局限于催化剂、特种玻璃、医学等传统领域,而在磁流体发电、离子推进器和钙钛矿电池等新型能源领域也有了一席之地。我国的铷铯资源主要存在于矿石和盐湖卤水中,从矿石中提取铷和铯的工艺比较成熟,主要有硫酸浸出法和焙烧—水浸法,仍存在工艺流程复杂,能量消耗大等问题,且大量尾气排放会对环境产生一定影响,不符合绿色产业理念,对实现我国的“双碳”目标具有较大的影响。从盐湖卤水中提取铷铯一般采用溶剂萃取法和离子交换法等技术,具有工艺流程简单、连续性强、能耗低、低排放等优势,具有更广阔的发展前景。本文综述了铷铯的资源现状、目前的提取难点和现阶段技术研究进展,深入探讨了硫酸浸出法、焙烧—水浸法、萃取法和离子交换法等技术的优缺点,并展望了未来铷铯提取技术的发展方向。
英文摘要:
      With the rapid development of science and technology in recent years, rubidium and cesium are not limited to traditional fields such as catalyst, special glass and medicine because of their excellent physical and chemical properties, but have a place in high-tech fields such as magnetohydrodynamic power generation, ion thruster propellant and new energy sources such as perovskite solar cells. Rubidium and cesium resources in China mainly exist in ores and brine of salt lakes, the process of extracting rubidium and cesium from ores is relatively mature, mainly sulfuric acid leaching method and roasting-water leaching method, there are still problems such as complex process flow and large energy consumption, and a large amount of tail gas emission will have a certain impact on the environment, which is not in line with the concept of green industry, and has a great impact on the realization of China""s It is not in line with the green industry concept and has a great impact on the realization of China""s "double carbon" target. The extraction of rubidium cesium from salt lake brine generally adopts technologies such as solvent extraction and ion exchange method, which have the advantages of simple process, strong continuity, low energy consumption and low emission, and have broader development prospects. This paper reviews the current status of rubidium cesium resources, the current extraction difficulties and the progress of technical research at the present stage, discusses in depth the advantages and disadvantages of sulfuric acid leaching, roasting-water leaching, extraction and ion exchange methods and other technologies, and looks forward to the future development direction of rubidium cesium extraction technology.
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